Forty years after the reactor explosion at Chernobyl, now commonly referred to as Chornobyl, tiny radioactive particles between 8 and 50 micrometers across remain in the environment. Entering affected areas still requires protective clothing, and the long-term behaviour of these particles has been difficult to predict.
Using synchrotron X-ray diffraction at the Rossendorf Beamline in Grenoble, physicist Tobias Weissenborn of Leibniz University Hannover and crystallographer Dr. Christoph Hennig of the Helmholtz-Zentrum Dresden-Rossendorf analysed six particles recovered from Ukrainian soil samples. Each particle was rotated in an X-ray beam focused to about 100 micrometers and measured from 2,000 different angles.
The researchers identified three classes of particles. Some remain chemically and physically similar to the nuclear fuel uranium dioxide. A second group formed when melted fuel combined with zirconium, the metal used in the fuel's protective cladding, leaving particles partially or fully encased in or fused with the zirconium layer. The third type formed when the reactor's graphite moderator caught fire and burned for ten days, oxidising the fuel into fragile uranium oxides such as U3O8 that can readily break apart into microscopic fragments and be carried by wind.
A surprising result was that, despite four decades of exposure to the environment, the nuclear fuel inside the six particles had retained much of its original crystal structure. That stability could slow the release of radioactive substances, allowing particles to hold fission products in place rather than quickly leaking contaminants into soil and water.
The authors caution against broader conclusions. "Every single particle has a different structure," Weissenborn warned, noting that only six particles from two locations were studied. Even with more data, he said, universal statements about health risks would remain impossible, because persistent outlier particles could release radionuclides long after others have broken down.
The findings therefore do not suggest the Chernobyl Exclusion Zone restrictions can be lifted any time soon. Weissenborn and Hennig are continuing experiments on highly radioactive transuranic phases in the debris to better understand how the materials change over time.
