Superconductors conduct electricity with zero resistance, a property that could transform computing, energy grids, and transport. But superconductivity typically requires extremely cold temperatures, limiting its practical use. In conventional superconductors, free electrons pair into Cooper pairs at the critical temperature and condense into a low-energy quantum state.
Back in 2007, scientists predicted a more exotic form of electron movement, called a pair density wave (PDW), in which Cooper pairs move in ripple-like patterns. Now, using a custom-made high-quality sample of uranium ditelluride and a vector magnetic field scanning tunneling microscope (STM), the team has detected clear signatures of PDWs. "PDWs are the Cheshire Cat's grin of superconductivity," said physicist Eduardo Fradkin. "They are the vestige that remains once the phase itself has disappeared."
The crucial advance: the PDWs were observed not only below the critical temperature of about 2.1 Kelvin but also at temperatures significantly above it. "We even showed that the modes persist above the temperature at which superconductivity disappears, a tell-tale theoretical prediction that has not been convincingly observed before now," said physicist Vidya Madhavan.
The researchers combined experimental data with theoretical models to confirm the patterns were intrinsic. "Thanks to new methods for growing higher-quality samples, we were able to observe spectral signatures that respond to temperature and magnetic fields exactly as pair density waves should," Madhavan added.
This does not mean bulk superconductivity occurs at higher temperatures in this material, but it demonstrates that Cooper pairs can exist outside the full superconducting state, potentially offering clues to designing superconductors that work at more practical temperatures.
Physicist Julian May-Mann from Stanford University noted the difficulty of identifying PDWs. "Confirming the existence of a PDW requires both high-quality experimental data as well as careful theoretical analysis," he said. Understanding how PDWs relate to charge density waves will be central to future experimental interpretation.