Researchers at Texas A&M University have reviewed a class of materials called salogels, which could help reduce the energy buildings burn on heating and cooling.
Salogels are polymer gels loaded with hydrated salts that trap water inside their crystals. They work as phase-change materials (PCMs), absorbing thermal energy as they melt and releasing it as they solidify. Compared to wax-based PCMs like paraffin, these hydrated salts can store more than twice as much heat per volume. They are also non-flammable and can be cheap, with some being industrial byproducts.
Previous attempts to use such salts in construction were hampered by leaking and separation when melted. Salogels solve this by using a polymer network to hold the salts in place. Reversible polymer bonds allow the material to retain 80% to 95% of its heat-storage capacity.
Kartik Kumar Rajagopalan of the university's Soft Matter Facility, one of the study's authors, said the materials represent "a shift from simply storing heat to engineering multifunctional materials that combine thermal energy storage and conversion."
The research proposes two building applications. A passive route embeds the gel in roofs, walls, or windows, letting it ride the day-night temperature swing. A dynamic route loads it into modules for air-conditioning or water heaters. Small-scale tests have been promising. In a 3D-printed house, a salogel wall coating kept interiors cooler in the day and warmer at night. In windows, the gel turns transparent and cools during melting, then turns opaque and releases heat as it crystallizes.
Significant hurdles remain. The best heat-storing gels are soft, while firmer gels store less energy. Some salts can also stay liquid below their freezing point, a problem the polymer network helps with but does not fully solve. The longevity of the materials and their real-world energy savings are still unknown.
The authors propose the use of AI and simulation to develop new polymer-salt combinations, and suggest salt blends with tunable melting points. The final aim is a tough, recyclable material that can perform for years inside buildings.
